1- (1-Adamntylcarbonyl) proline (ACA) moetsi oa phofo CAS No.: 35084-48-1 98% bohloeki min.bakeng sa lisebelisoa tsa tlatsetso
Lihlahisoa tsa lihlahisoa
| Lebitso la sehlahisoa | 1-(1-Adamntylcarbonyl) proline |
| Lebitso le leng | 1-(1-ADAMANTYLCARBONYL)PYRROLIDINE-2-CARBOXYLIC ACID; 1-(ADAMANTANE-1-CARBONYL) -PYRROLIDINE-2-CARBOXYLIC ACID; 1-(1-Adamantylcarbonyl)proline;L-Proline, 1-(tricyclo[3.3.1.13,7]dec-1-ylcarbonyl)- |
| Nomoro ea CAS. | 35084-48-1 |
| Mokhoa oa limolek'hule | C16H23NO3 |
| Boima ba molek'hule | 277.36 |
| Bohloeki | 98.0% |
| Ponahalo | Phofo e tšoeu |
| Ho paka | 1kg/ mokotla 10kg/moropa 25kg/moropa |
| Kopo | Nootropic |
Kenyelletso ea sehlahisoa
1-(1-Adamantylcarbonyl) proline ke motsoako oa phenylalanine, o tsejoang hape e le adamantylproline kapa Ad-Pro.E sebelisoa haholo-holo e le sesebelisoa kapa reagent ea chiral resolution ho organic synthesis.Liphuputso li bonts'itse hore 1-(1-Adamntylcarbonyl) proline e ka etsa hore ho be le li-asymmetric nucleophilic addition reactions, joalo ka karabelo lipakeng tsa aldehydes le alkylene azides, karabelo lipakeng tsa aldehydes le sulfuryl folate, karabelo lipakeng tsa aldehydes le nitromethane, joalo-joalo. sesebelisoa sena se na le ts'ebetso e matla ea ho eketsa ho alkylene azides.1-(1-Adamntylcarbonyl) proline e ka boela ea susumetsa maikutlo a asymmetric amination.1-(1-Adamntylcarbonyl) proline e ka boela ea sebelisoa e le tšubuhlellano ea chiral ho etsa hore ho be le asymmetric alcoholylation .Mohlala, e ka sebetsana le lino tse tahang ka aldehydes kapa ketone ho fana ka lihlahisoa tse tsamaellanang tsa aldol kapa hydroxyketone.1-(1-Adamntylcarbonyl) proline, joalo ka motsoako oa chiral organic, e na le ts'ebetso e ntle haholo ea ho thusa.Ka lebaka la thepa ea eona e ikhethang ea chiral, e sebelisoa haholo ho chiral organic synthesis, ho kenyeletsoa karabelo ea tlatsetso ea asymmetric nucleophilic, karabelo ea amination, karabelo ea ho noa joala, jj.
Sebopeho
(1) 1-(1-Adamntylcarbonyl) proline ke phofo e tšoeu kapa e bosoeu e nang le ho qhibiliha hamonate.E na le ho qhibiliha ha tlaase metsing, empa hangata e na le ho qhibiliha hamonate ka har'a metsoako ea tlhaho.Ke motsoako o tsitsitseng o ka bolokoang nako e telele mocheso oa kamore.
(2) 1-(1-Adamntylcarbonyl) proline ke molek'hule ea chiral e nang le li-enantiomers tse peli.Sebopeho sa eona sa chiral se etsa hore e sebelisoe haholo ho chiral synthesis.Hangata, ho lokela ho sebelisoa isomer e le 'ngoe feela ea chiral ka lebaka la induction ea eona e ntle ea chiral.
3E ka boela ea sebelisana le limolek'hule tsa substrate ka ho etsa li-hydrogen bond kapa ion pairing ho ntlafatsa katleho ea karabelo le khetho.
(4) 1-(1-Adamntylcarbonyl) proline e sebelisoa haholo ho chiral organic synthesis le catalytic reactions.E ka sebelisoa e le reagent ea chiral resolution, chiral catalyst, chiral inducer, joalo-joalo.
Lisebelisoa
1-(Adamanane-1-carbonyl) -pyrrolidine-2-carboxylic acid ke motsoako o nang le naetrojene, o mosoeu kapa o mosoeu, o sebelisoang e le bohareng kapa meriana e sebelisoang ho matlafatsa boko, ho khothalletsa bohlale, ho khatholla le ho khothalletsa nts'etsopele ea methapo ea boko e senyehileng.
